It is common for punters and bookmakers to express sports betting odds in terms of chances or probabilities of the horse winning. This is achieved by converting the betting odds to a %chance as shown in Table 1.
In a fictional horse race of four runners, where each horse has an equal chance of winning, the true betting odds will be 3/1 [see Table 2 race 1].

A £1 stake on each runner at 3/1 will leave the punter "all square" - no matter what the result. Each horse has a 1 in 4 (or 25%) chance of winning. The sum of the chances for each horse winning the race is 100%.
In reality, the bookmaker includes a race over-round, so the sum of the individual %chances of each horses is > 100%. Now the betting odds are in the bookmakers favor and the punter will no longer be "all square" if all horses are backed. The amount > 100% is the degree to which the betting odds are in favor of the bookmaker [see Table 2 race 2].
Bookmaking is founded on the principle that the betting book has an over
round and that the bookmaker will make a profit no matter what the result.
The successful punter will follow horses when the betting odds are in their
favor. i.e. the true %chance of the horse winning the race are greater than
those being offered by bookmakers.
N.B. Typical over-round is 2% per runner. So a 4 runner race could be expected
to be 108%.
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